Liquefaction process is carried out in a low temperature typically at 250350°C and high H2 pressure in the range of 520 MPa, and a catalyst is used to assist the process to produce biooil [59]. This technique is very suitable for moisture feedstock like microalgae as it has very high water content (>80%) and no drying process is required [66].
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An improved coal liquefaction process is provided which enables conversion of a coaloil slurry to a synthetic crude refinable to produce larger yields of gasoline and diesel oil. The process is characterized by a twostep operation applied to the slurry prior to catalytic desulfurization and hydrogenation in which the slurry undergoes partial ...
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Coal Liquefaction It is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices,Also called Coal to Liquid (CTL) technology. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2).
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In principle, the process of coal liquefaction involves chemical compounds which also occur in other carbochemical or petrochemical processes. It is well known that a number of these substances may be carcinogenic, teratogenic or mutagenic. The concentration of benzo(a)pyrene in coal liquefaction products can be between 50 and 60 μg g −1.
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3. Features of NEDOL Process˜ The NEDOL Process is a coal liquefaction process developed exclusively in Japan. The process has integrated the advantages of three bituminous liquefaction processes (Direct Hydrogenation Process, Solvent Extraction Process, and Solvolysis Process), thus providing superiority in both technology and economics. The
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article{osti_, title = {Novel use of residue from direct coal liquefaction process}, author = {Yang, Jianli and Wang, Zhaixia and Liu, Zhenyu and Zhang, Yuzhen}, abstractNote = {Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of ...
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The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
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The different liquefaction mechanisms of lignite including free radical, oxidation, alkanolysis, and hydrogenation lead to the corresponding products: preasphaltene and asphaltene, mixed carboxylic acids, mixed esters and ethers, and cyclic compounds, respectively.
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The principal direct liquefaction processes are: 1. Extraction. Some bioderived and waste materials yield an oil product by extraction that can directly be used as feed material for refining.
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Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
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The Hcoal process is to be installed at a site in Kentucky and will have a 600 tons/day coal capacity, small compared to the coal gasification demonstration plants under study. The comparative lack of activity in coal liquefaction compared to gasification is the result of the factors described in Section VII,C .
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Indirect liquefaction processes require first gasifying the solid feedstocks into a syngas. Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of ...
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Plasmochemical hydrogenation of coal is a new process of direct production of acetylene and alkenes in the gaseous phase, in contrast to traditional processes of coal hydrogenation (liquefaction). Propanebutane mixture (50% C 3 H 8 +50% C 4 H 10), 200 t −1, is used as a hydrogenating agent instead of hydrogen, 2000 t −1.
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Indirect liquefaction of coal (ICL) has been found to be the most commercially viable process involving the gasification of coal. ICL includes two steps; in the first step, coal is converted into syngas ( Coal+H2OCO+H2), and during the last step, syngas is synthesized in the presence of a catalyst into liquid fuels.
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Petroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
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(A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
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The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FTIR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible ...
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Liquefaction. Coal liquefaction is a process of converting coal into liquid fuels or petrochemicals. There are several processes to accomplish this task. The two most common are the indirect route and the direct route [58, 59].
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What is coal liquefaction? Also called Coal to Liquid (CTL) technology, it is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2). The synthetic gas can be liquefied to its fuel ...
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the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
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Investigation of the nonintegrated twostage coal liquefaction (NTSL) process was initiated at the Wilsonville Advanced Coal Liquefaction R and D Facility during May 1981 when the HOil hydrotreating unit came successfully online. The primary objective of this investigation is the development of a commercially feasible method of efficient ...
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Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
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On the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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article{osti_, title = {Catalyst withdrawal and addition in a coal liquefaction process}, author = {Simone, A A and Ogren, D F}, abstractNote = {The catalyst is withdrawn from a coal hydroliquefaction reactor while it is maintained on stream by withdrawing a portion of the catalyst, in a separate stream, dispersed in product from the liquefaction zone, with such withdrawn stream being ...
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid ...
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Abstract. The frontend design of a direct coal liquefaction process for the conversion of lignite into coal liquids by solvent extraction was investigated. The experimental work focused on ...
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New study shows liquefied natural gas might be worse for climate change than coal The findings have major implications for global climate goals and for the United States, which became the world ...
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Relative to the Base Case, product cost reductions for Cases 13 were roughly estimated as follows: Case % Cost Reduction[7] 1 20 2 22 3 28 B. Wyoming Coal Case To determine the effect of coal type on the EDS liquefaction process, ERE performed a study design for subbituminous Wyodak coal.[12][14][15] This design was patterned after the 1975/ ...
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An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogenrich gases at ...
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