Bauxite residue (BR) is a hazardous industrial waste and also becomes an important reserve of rare earth elements (REE). An elegant process for achieving separation of REEs against silica from an ironremoved BR was established in this paper through selective leaching of silica with simultaneous enrichment of REEs.
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Therefore, the leaching process with dilute HNO 3 has been performed and optimized at a pilot scale for the recovery of scandium from bauxite residue . According to Petrakova et al., leaching with nitric acid could be a problem due to the absorption of nitrate ions on the residue, so that large volumes of water are needed for their removal [ 43 ].
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Hall's process for leaching of alumina from bauxite: (1) Bauxite ore and sodium carbonate are fused toghether to convert aluminium oxide into soluble sodium metaaluminate. The insoluble residue contains the impurities of silica and iron oxide. The fused mass is treated with water.
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Thus, Bayer process is economically unsuitable to process the bauxite resource with silica content greater than 8% by weight (A/S≤) . As to the bauxite with A/S of, the A/S in concentrate fed to the Bayer process can be increased by predesilication with flotation dressing [ 26, 27 ], roastingleaching process [ 28, 29 ], or ...
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Thus, this process doesn't look compatible with laterite where the iron content is much higher than typical lowgrade bauxite. Hence, an alternative acid leaching extraction was planned. For any earth material extraction process, the study of the kinetic behavior of element extraction is crucial to make the process efficient.
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The leaching process with dilute HNO 3 was performed at pilot scale and optimized for the extraction of scandium from bauxite residue ( OchsenkühnPetropoulou et al., 2002 ). Xue et al. (2010) found that at a reaction temperature of 90 °C and an L/S ratio of 3:1, over 80% of the scandium in bauxite residue could be leached by H 2 SO 4.
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Bauxite residue, known as red mud, is a byproduct of alumina production using the Bayer process. Currently, its total global storage amounts to over billion tons, including about 600 million ...
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Acid leaching followed by thermal activation and water or alkaline solution leaching followed by lime or sodalime mixture sintering are the main developed processes to produce alumina from nonbauxite ores [].However, removing silica due to its solubility before carbonation of aluminate solutions by alkaline leaching and removing iron solubilized before alumina precipitation by acid leaching ...
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In this study, bauxite residue was directly leached using the Brønsted acidic ionic liquid 1ethyl3methylimidazolium hydrogensulfate. Stirring rate, retention time, temperature, and pulp density have been studied in detail as the parameters that affect the leaching process. Their optimized combination has shown high recovery yields of Sc, nearly 80%, and Ti (90%), almost total dissolution ...
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The ideal conditions for the leaching process was determined through response surface methodology (RSM) to be H3PO4 concentration of mol/L, L/S ratio of 11 mL/g and leaching temperature of 40 ...
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In this study, metal extraction from bauxite ore was carried out with a twostage leaching process. At the first stage, bauxite ore was leached under atmospheric conditions with oxalic acid, iron ...
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The circulation liquid and lime (75% active CaO) for Bayer leaching were obtained from Guizhou, China. Methods. Three different AlFe recovery processes can be found in Fig. shown in Fig. 2, the LRS process means that the bauxite is firstly subjected to Bayer leaching, followed by magnetic roasting of red mud, and then, the roasted red mud would be magnetically separated for ...
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The leaching process with dilute HNO 3 was performed at pilot scale and optimized for the extraction of scandium from bauxite residue (OchsenkühnPetropoulou et al., 2002). Xue et al. (2010) found that at a reaction temperature of 90 °C and an L/S ratio of 3:1, over 80% of the scandium in bauxite residue could be leached by H 2 SO 4 .
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Brazil is the third largest country in the world in bauxite resources and production [1, 2].This ore is the raw material for alumina production through the Bayer process, where sodium hydroxide is used as leaching agent, which enables the selective leaching of alumina.
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Bauxite residue (BR), an alkaline industrial waste, is a major byproduct of the alumina production process known as the Bayer process. The Bayer process generates a byproduct known as bauxite residue (red mud). This residue was leached with sulfuric acid in a pilot plant of Mytilineos to recover scandium. Scandium was selectively recovered in pilotscale experiments using ion exchange.
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The process involves baking of bauxite residue with sulfuric acid (12 mL/g, 120200 °C, 224 h) to generate metal sulfates and further decomposition of sulfates (except RE) at high temperatures (600800 °C) and water leaching to dissolve REEs [14,15,16,17]. The process is not costeffective due to the very low starting concentration ...
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To uncover the mechanism of REEs leaching process from bauxite residue in the H 2 SO 4 system (without microwave pretreatment), liquid samples were taken over time up to 60 min at all four ...
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In this study, a novel process of lowtemperature sulfating roastingwater leaching is presented to extract vanadium from the bauxitetype vanadium ore. Addition of sulfuric acid enhanced the ...
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Principle processflow diagram of bauxite leaching with HCl based on reference [112]. Many metallic elements in bauxite can be leached in an acid solution. Thus, iron, aluminum or other metallic elements are leached and recovered together during the acidleaching process. However, some problems with acid treatment remain, including severe ...
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The study showed the change in the limiting stage of the alkaline leaching process after water treatment, with the activation energy growing from to kJ/mol.
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In general, the lithium content in bauxite ore is negatively correlated with the alumina content,, the lithium content in bauxite decreases with increasing Al 2 O 3 content. 25,28 Lithium in bauxite tailings 27 can be recovered using acid leaching; however, this leaching process is not selective and the leachate purification process is ...
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The Bayer process is used worldwide for the alumina production. This process involves the alkaline leaching of bauxite to extract Al, followed by the precipitation of Al(OH) 3 to recycle the solution [1,2,3].The leaching process results in the formation of a solid residue, commonly referred to as a bauxite residue, which consists of iron minerals, hydrous aluminosilicates, which are formed ...
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Hint: Baeyer's process is a process used for the leaching of bauxite ( an ore of aluminium ). The reagent chosen should be the one which is a strong reducing agent. Complete answer: Leaching is a process which consists of treating the powdered ore with a suitable reagent such as acid base or other chemicals which can selectively dissolve the ore but not the impurities.
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DOI: /materproc Corpus ID: ; The Efficient Use of Sulfuric Acid in Bauxite Residue Leaching article{Toli2023TheEU, title={The Efficient Use of Sulfuric Acid in Bauxite Residue Leaching}, author={Aikaterini Toli and Dimis Kotsanis and Maria Psoma and Danai Marinos and Panagiotis Davris and Efthymios Balomenos and Dimis Panias}, journal={RawMat 2023}, year ...
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Gibbsitic bauxite from Australia was leached by hydrochloric acid in this work. Analysis on kinetics for the extraction of Al 2 O 3 was quantitatively studied. It was concluded that the hydrochloric acid leaching process of gibbsitic bauxite was controlled by chemical reaction. Moreover, the mechanism for the dissolution followed the equation ...
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Verified by Toppr. Bauxite gets dissolved in hot concentrated NaOH but the impurities do not dissolve in this. So, the method of concentration used for bauxite ore is Leaching. Solve any question of General Principles and Processes of Isolation of Elements with:. Patterns of problems.
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At the same time, as a secondary resource, its aluminum content can reach 50%, which is close to that of mediumgrade bauxite; thus, it can be used as a substitute for bauxite resources. We propose a new method for extracting aluminum from fly ash via leaching. By designing the thermal reaction system of the molten brine, highpurity hydroxyl ...
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The HCl leaching studies of bauxite indicated that as the concentration of HCl acid increases, the iron content reduces substantially, but at the same time, loss of alumina takes place. The change in bauxite colour from reddish brown to light colour indicated leaching of ore. ... In order to minimize the input material for the leaching process ...
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A closedloop valorization process, combining carbothermic smelting and acid baking water leaching was developed to recover scandium, aluminum, and iron from bauxite residue, a major side product of aluminum production. This process employs carbothermic smelting to recover 99% of the iron in the starting residue as crude metallic iron, which can be separated from slag that contains ...
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In the leaching method, bauxite ore is digested with a concentrated solution of N a O H that produces X. When C O 2 gas is passed through the aqueous solution of X, a hydrated compound Y is precipitated. X and Y are N a [A l (O H) 4 ] and A l 2 O 3 ⋅ x H 2 O respectively.
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The lateritic bauxite hydrochloric acid leaching process showed that when the ore granularity was less than 55 μm, the liquid/solid ratio (L/S ratio) was 100:7, the leaching temperature was 373383 K, the leaching time was 120 min and the HCl concentration was 10%, both the leaching rates of Al and Fe were over 95% . But the hydrochloric ...
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Red mud (RM) is a waste generated during bauxite processing for alumina production. The most common method for bauxite processing is the Bayer process, where raw material is digested under high pressure by NaOH to obtain a pregnant sodium aluminate solution [].During highpressure leaching, nonsoluble elements such as iron, titanium, and refractory or precipitated during washing step aluminum ...
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In this process, bauxite residue is smelted at 1500 °C or higher in presence of a flux and a reductant to produce pig iron and slag. Alumina in the produced slag is mainly in the form of calcium aluminate that can be treated with Na 2 CO 3 solution. The leach residue generated from this process is known as gray mud.
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In this study, a novel process has been developed to extract lithium as lithium phosphate from bauxite mine tailings, which includes: 1) leaching with mixed acid (H 3 PO 4 + H 2 SO 4), 2) leachate neutralization, and 3) Li 3 PO 4 preparation. Mixed acid was used to effectively leach lithium (Li) without roasting pretreatment, the Li leaching ...
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