Bayer's method: In this method, bauxite powder is taken and concentrated (45%) and sodium hydroxide solution is added and then heated in a closed vessel at 433 K temperature and 5 to 6 bars of pressure, for 6 to 8 hours, so that aluminium oxide present in bauxite is converted into sodium aluminate which is soluble in water. In bauxite, in ...
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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The chemical and physical properties of bauxite residues are determined by the nature of the bauxite and the effect of the Bayer process. The technology and operating procedures at individual refineries ... together with a wide range of other oxides which will vary according to the country of origin of the bauxite. The high concentration of ...
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Bauxite residue is the byproduct of alumina production and is generated in the Bayer process when bauxite is digested in hot NaOH under elevated temperature and pressure. ... H 2 C 2 O 4 concentration, contact time and temperature had the most pronounced effect on the extracted Ga (ranging from to mg/kg while leaving the other factors ...
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The Bayer process, with various modifications, is the most widely used method for the production of alumina, and all aluminum is produced from alumina using the HallHéroult electrolytic process. Refining the ore. aluminum processing: Bayer process. Principal operations in the Bayer process of refining bauxite to alumina. (more) There are a ...
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The bauxite slurry typically has lower caustic concentration liquor as the bauxite is received with some humidity that acts to dilute the liquor which mixes with it at the start of the process. Thus, the step to single stream digestion not only provides an extra heat sink to improve energy efficiency, it also reduces the heater tube caustic ...
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The bauxite (alumina content ∼5459 wt%) used as the raw material in the Bayer process for the synthesis of alumina was obtained from a mine at Weipa in Queensland, bauxite ores were crushed to a particle size of <10 μm using an attrition mill. Table 1 lists the composition of bauxite supplied from the support company. A 5 N sodium hydroxide solution was used for the ...
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3 ), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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Li et al. [42] have further proved that the accelerated conversion of goethite and Algoethite by adding 2 g/L glycerol during the Bayer process favored the beneficiation and concentration of iron ...
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S 2 2− in high sulfur bauxite undergoes gradual transformation into S 2 O 3 2−, SO 3 2−, and SO 4 2− during the Bayer process, which leads to adverse effects in production . For example, it causes corrosion of steel equipment [ 3, 4 ], an increase in alkali consumption [ 5 ], a reduction in heat transfer efficiency [ 6 ], and affects ...
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During the electrolysis process, the potential of the cathode relative to the reference electrode was measured as a function of the current at different concentrations of solid (100300 g L −1) and suspension temperatures (95120 °C).
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The slurry from desilication is mixed with NaOH (P13/MX101) up to concentration of 10%, ... The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to ...
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• The purification of bauxite using Bayer's process. • The electrolytic reduction of anhydrous Al 2 O 3 by Hall and Herault's process. • The last step is the purification of impure aluminium by Hoope's process . In Baeyer's process, impure bauxite is converted into pure alumina. The conversion process involves mainly three reactions:
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The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to aluminium. ... (Na2Ox or K2Ox) increases with an increase in concentration of the counter ion ...
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Alumina is extracted from bauxite by the Bayer process. The waste slurry generated in this process is called red mud and its solid fraction is called bauxite residue. About 12 metric tonnes of bauxite residue is generated for each tonne of alumina produced ( Kumar et al., 2006 ). The global annual generation of bauxite residue is around 120 ...
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Alumina Production (Bayer Process) The aluminium production starts with the production of alumina from bauxite according to the socalled Bayer process. In the Bayer process, caustic soda (NaOH) is used to extract alumina from bauxite in digesters. High temperatures and pressures are required for this process (Kuenen et al. 2016).
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A simplified process flow diagram of the Bayer process used at the Wagerup refinery is presented in Figure 6. Bauxite Grinding and Slurry Storage Bauxite is ground to less than mm particle size at the refinery, using semiautogenous grinding mills (SAG and/or Ball mills) to ensure sufficient solidliquid contact during the
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on the Bayer process. Predesilication characteristic of the bauxite, the effects of digestion temperature and retention time, concentration of Na20 and amount of CaO addition on AI20 3 digestion efficiency in Bayer process, the settling characteristics ofthe red mud were determined. The bauxite in
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Red mud is a byproduct of alumina production, and its disposal can have severe environmental consequences. This study experimentally investigates the feasibility of using red mud from the Bayer process for cemented paste backfill (CPB). Different binders and activators were used to improve the mechanical properties, water resistance, and environmental behaviors of red mudbased CPB. In ...
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The first step is to heat the bauxite ore to temperatures of 200°c along with a sodium hydroxide solution. This will convert the aluminium oxide to a solution of sodium aluminate. The silica will dissolve itself in the process. The chemical equation is. Al 2 O 3 + 2 NaOH → 2 NaAlO 2 + H 2 O.
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The production process of Bayer alumina is shown in Figure 2. In the Bayer process, bauxite is leached with a hot solution of sodium hydroxide (NaOH) at temperature of 150240°C and at 16 atm pressure . The aluminum minerals in the bauxite may be present as gibbsite (Al(OH) 3), boehmite (AlOOH) or diaspore (AlOOH) . The different forms of ...
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Red mud is a slimy caustic residue generated from alumina refining of bauxite ores. During the alumina extraction process, about 35 %40 % of the bauxite ores go into the residue as highly alkaline red mud slurry (pH ) which contains 15 %40 % of solid phase in volume [1, 2].Depending on the quality of bauxite ores, producing 1 t alumina basically generates t red mud [].
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The Bayer process is used for refining bauxite to smelting grade alumina, the precursor to aluminum. Typically, depending upon the quality of the ore, between and tonnes of bauxite is required to produce 1 ton of alumina. The Bayer process involves the digestion of crushed bauxite in the concentrated sodium hydroxide (caustic) solution at
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Crushed bauxite is treated with moderately concentrated sodium hydroxide solution. The concentration, temperature and pressure used depend on the source of the bauxite and exactly what form of aluminum oxide it contains. Temperatures are typically from 140°C to 240°C; pressures can be up to about 35 atmospheres.
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The Bayer Process. The Bayer Process, which is used by about 80 active plants worldwide, is the primary method of producing aluminum from bauxite. Bauxite ore is dissolved in sodium hydroxide, or lye, at a high temperature and pressure. Then, the alumina and bauxite ores are separated by washing out the waste (red muds or sands) from the alumina.
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Bayer's process for concentration of bauxite. Ans. Bayer's process is used to obtain pure aluminium oxide from bauxite ore. The bauxite ore is concentrated by chemical separation. Bauxite contains impurities like iron oxide and silica. The bauxite ore is powdered and heated with sodium hydroxide under high pressure in the furnace.
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Aluminum production from bauxite is achieved with the Bayer process, which is a hydrometallurgical method. However, in the Bayer process, in time, it is possible to encounter problems such as the formation of excessive amounts of red mud in aluminum production, its environmental risks, its requirement of large storage sites, the excessive production of reactants by ores with low silica modulus ...
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The Bayer process is the principal method for the production of alumina from bauxite worldwide. The modern version of the process (developed in the 1880's) still maintains the key steps of dissolution of aluminarich minerals into hot caustic solution, separation of the insoluble phases, followed by gibbsite precipitation and calcination of the gibbsite to alumina (Al 2 O 3).
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One of the potential sources of rareearth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red ...
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Bayer process, bauxite is mixed with caustic soda, or sodium hydroxide, and heated under pressure. ... The maximum concentration of alumina dissolved in the caustic, known as the ratio (as Al 2 O ...
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The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
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Bayer process is about the production of alumina through the refining of aluminum ore (bauxite). The red mud is insoluble slurry waste that contains different types of oxides. Tremendous amount of this slurry is disposed every year (Marwaha et al., 2018 ).
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For the same grade of bauxite ore, using the traditional Bayer process, the theoretical maximum alumina dissolution rate is % and the Na 2 O mass fraction in the slag is about % (A/S = 1 and N/S = in the red mud), while the actual dissolution rate of the Bayer process bauxite ore in this alumina plant is about 70%, which shows ...
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Alumina Extraction Problem. In the standard Bayer Process for refining bauxite to produce alumina, the dissolution of the alumina in the ore to form sodium aluminate is accomplished in autoclaves under high pressures varying from 70 to 200 pounds per square inch. However, some lateritic bauxite ores are readily soluble in caustic, making it ...
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